A comparison of mass isotopomer dilution methods used to compute production of vldl fatty acids in vivo in human subjects. Chinkes;, David L., Asle Aarsland, Judah Rosenblatt, and Robert R. Wolfe. Metabolism Unit, Shriners Burns Institute; and Departments of Surgery and Anesthesiology, The University of Texas Medical Branch, Galveston, Texas 77555
APStracts 3:0076E, 1996.
The recent development of mass isotopomer distribution methods represents an important new tool for quantifying synthetic rates. These methods allow precursor enrichment to be determined indirectly from the enrichment of the product, thus sidestepping the often difficult problem of measuring the precursor enrichment. Two different methods have been described to compute synthetic rates by this general approach by Hellerstein's and Kelleher's labs and variations of these basic approaches have also been presented by Lee and by ourselves. A comparison between the different methods has never been reported. In this paper we take a specific application, calculation of the fractional rate of incorporation of acetylCoA into VLDL bound palmitate, and compare the results obtained from all of the mass isotopomer methods using the same data set obtained in vivo in human subjects. We found that it is critical that the measured background isotopomer distribution of palmitate is used rather than the theoretical background isotopomer distribution. We also found that the different methods give comparable precursor enrichments and comparable fractional synthesis rates, provided that the enrichments in Kelleher's method are properly weighted. Thus the choice of method to use is a matter of personal preference.

Received 5 July 1994; accepted in final form 20 March 1996.
APS Manuscript Number E248-4.
Article publication pending Am. J. Physiol. (Endocrinol. Metab.).
ISSN 1080-4757 Copyright 1996 The American Physiological Society.
Published in APStracts on 23 April 96