Use of the labeling pattern of liver glutamate to calculate rates of krebs cycle and gluconeogenesis. Large, Val[acute]erie, Henri Brunengraber, Mich[grave]ele Odeon, and Michel Beylot. INSERM U. 197, Lyon, France and Department of Nutrition, C.W.R.U., Cleveland, USA
APStracts 3:0195E, 1996.
It has been proposed to use the labeling pattern of hepatic glutamate during infusion of L[3-13C] or [3-14C]lactate in order to calculate rates of Krebs cycle activity and gluconeogenesis. We tested the validity of this approach by perfusing isolated rat livers (48h starved) with pyruvate + lactate (10 % enriched with [3-13C]lactate) without (control) or with infusion of glucagon (to inhibit pyruvate kinase), mercaptopicolinate (to inhibit phosphoenol-pyruvate carboxykinase) or dichloroacetate (to stimulate pyruvate dehydrogenase). Compared to control experiments glucagon increased glucose output (p<0.05) and decreased the calculated flux through pyruvate kinase (p<0.05). Mercaptopicolinate suppressed almost totally glucose production and reduced dramatically the calculated gluconeogenic rate and flux through phosphoenolpyruvate carboxy-kinase (p<0.001). Dichloroacetate increased moderately the calculated flux through pyruvate dehydrogenase (p<0.05). In experiments with perfused livers from fed rats, the calculated gluconeogenic rate and flux through phosphoenolpyruvate carboxykinase were very low compared to control experiments (p<0.001) whereas the pyruvate dehydrogenase flux was increased (p<0.05). Therefore the expected modifications of Krebs cycle activity and gluconeogenic rate were clearly detected using the labeling pattern of glutamate and the model proposed by Magnusson et al. Except for the perfusions with mercaptopicolinate, the dilution by isotopic exchange in the oxaloacetate pool calculated from the model agreed with the actual dilution of enrichment between liver pyruvate and phosphoenolpyruvate. The present results support the validity of this approach to trace liver metabolism.

Received 15 April 1996; accepted in final form 21 August 1996.
APS Manuscript Number E193-5.
Article publication pending Am. J. Physiol. (Endocrinol. Metab.).
ISSN 1080-4757 Copyright 1996 The American Physiological Society.
Published in APStracts on 7 October 1996