Arginase activity in endothelial cells: inhibition by g -hydroxyarginine during high-output nitric oxide production. Buga, Georgette M., Rajan Singh, Shehla Pervin, Norma E. Rogers, Debra A. Schmitz, Christopher P. Jenkinson, Stephen D. Cederbaum, and Louis J. Ignarro. Departments of Molecular Pharmacology, Psychiatry, Pediatrics and Obstetrics & Gynecology, UCLA School of Medicine, Center for the Health Sciences, Los Angeles, California 90095
APStracts 3:0252H, 1996.
Rat aortic endothelial cells were found to contain both constitutive and lipopolysaccharide (LPS)-inducible arginase activity. Studies were performed to determine whether induction of nitric oxide synthase (NOS) by LPS and cytokines is accompanied by sufficient arginase induction to render arginine concentrations rate-limiting for high-output NO production. Unactivated cells contained abundant arginase activity accompanied by continuous urea formation. LPS induced the formation of both inducible NOS (iNOS) and arginase, and this was accompanied by increased production of NO, citrulline and urea. Immunoprecipitation experiments revealed the constitutive presence of arginase-I in both unactivated and LPS-activated cells, and arginase-II induction by LPS. Arginase-I and iNOS were verified by reverse transcriptase-polymerase chain reaction. The induction of large amounts of iNOS by LPS plus several cytokines resulted in the production of large quantities of NO, citrulline and NG -hydroxyarginine (NOHA) but urea production was markedly diminished. Decreased urea production was attributed to increased formation of NOHA, the precursor to NO and citrulline, and a potent inhibitor of arginase-I activity with a Ki of 10-12 [mu]M. Inhibition of iNOS activity by NG-methylarginine decreased NO and NOHA production and increased urea production. This study reveals for the first time that substantial arginase activity is present constitutively in rat aortic endothelial cells, a different isoform of arginase is induced by LPS, and intracellular arginase activity can be markedly inhibited during cytokine induction of iNOS because of formation of NOHA. The inhibition of arginase activity that occurs by NOHA during marked iNOS induction may be a mechanism to ensure sufficient arginine availability for high-output production of NO.

Received 29 February 1996; accepted in final form 15 May 1996.
APS Manuscript Number H202-6.
Article publication pending Am. J. Physiol. (Heart Circ. Physiology).
ISSN 1080-4757 Copyright 1996 The American Physiological Society.
Published in APStracts on 28 June 96