Contribution of cytosolic and membrane bound, 5_-nucleotidases to cardiac adenosine production. Darvish, Ahmad, Richard W. Pomerantz, Peter G. Zografides, and Patricia J. Metting. Laboratory of Cardiovascular Research, Department of Physiology and Molecular Medicine, and Division of Cardiology, Department of Medicine, Medical College of Ohio, Toledo, Ohio 43699
APStracts 3:0205H, 1996.
The purpose of this study was to evaluate the relative contributions of AMP-specific cytosolic 5_-nucleotidase and ecto-5_-nucleotidase to cardiac adenosine production and its regulation by ADP and Mg2+. 5_ -Nucleotidase activity was measured spectrophotometrically in the total homogenate, the 150,000xg supernatant fraction (cytosolic 5_ -nucleotidase), and the membrane pellet fraction (ecto-5_ -nucleotidase) of dog left ventricles. Increasing [MgCl2] over a range from 0 to 6 mmoles/L increased 5_-nucleotidase activity in both the supernatant and pellet; only cytosolic 5_-nucleotidase exhibited an absolute requirement for Mg2+. ADP (20-480 [mu]moles/L) activated supernatant and inhibited membrane-bound 5_-nucleotidase activity. At 80 [mu]moles/L ADP, 5 mmoles/L MgCl2, 100 [mu]moles/L AMP, and pH 7.3, the average 5_-nucleotidase activities of the supernatant vs. pellet were 147 (74% of total) and 51 (26% of total) nmoles/min/gm tissue, respectively. Total adenosine production in unfractionated samples of ventricular homogenates was decreased an average of 73% by specific inhibition of cytosolic 5_-nucleotidase using antibodies against the cytosolic enzyme, and 46% by specific inhibition of ecto -5_-nucleotidase with [alpha],[beta]-methylene adenosine 5_ -diphosphate (AOPCP). These findings support the hypotheses that 1) both cytosolic and ecto-5_-nucleotidase contribute to cardiac adenosine production in dog heart homogenates, 2) AMP-specific cytosolic 5_-nucleotidase activity exceeds ecto-5_-nucleotidase activity at physiological concentrations of ADP, AMP and Mg2+, and 3) Mg2+ is an important regulator of cardiac adenosine production via activation of both ecto- and AMP-specific cytosolic 5_-nucleotidases.

Received 21 October 1994; accepted in final form 15 April 1996.
APS Manuscript Number H942-4.
Article publication pending Am. J. Physiol. (Heart Circ. Physiology).
ISSN 1080-4757 Copyright 1996 The American Physiological Society.
Published in APStracts on 19 May 96