Effects of ischemia on intracellular sodium and phosphates in the in vivo rat liver. Xia, Zhao-Fan, Jureta W. Horton, Pi-Yu Zhao, Evelyn E. Babcock, A. Dean Sherry, Craig R. Malloy. Department of Surgery, Mary Nell and Ralph B. Rogers Magnetic Resonance Center (Department of Radiology), Department of Internal Medicine (Cardiology Division), Department of Veterans Affairs Medical Center, Dallas, Texas, University of Texas Southwestern Medical Centers, Dallas, Texas, Department of Chemistry, University of Texas at Dallas, Richardson, Texas and the: Research Institute of Burn and Trauma, Changhai Hospital, Shanghai, China
APStracts 3:0246A, 1996.
Metabolic factors which influence the transition from reversible to irre versible ischemic injury were studied in the rat liver in vivo using 31P NMR spectroscopy. Hepatic ischemia for 15, 35 or 65 minutes was produced by oc clusion of the hepatic artery and portal vein in rats. Ischemia caused a rapid decrease in [ATP]/[Pi] and pH within 5 minutes, but there was little change in these variables detectable by 31P NMR with longer periods of ischemia. After reperfusion, the [ATP] and [Pi] returned towards normal in livers exposed to 15 or 35 minutes of ischemia, but 65 min of ischemia was associated with only modest recovery in [ATP], and the [ATP] later decreased. Since the 31P NMR spectrum was similar after brief compared to prolonged ischemia, it appears that neither ATP depletion, Pi accumulation nor acidosis predict metabolic recovery. Hepatic intracellular sodium was also measured in separate groups of animals by 23Na NMR in the presence of a shift agent, thulium (III) 1,4,7,10 -tetraazacyclododecane- N',N'',N'''tetramethylenephosphonate (TmDOTP5 -), and by atomic absorption spectroscopy (AAS). Under baseline conditions, the concentration of intra cellular sodium [Na+]i was 15.2 mM by AAS and 16.5 mM by 23Na NMR. Although the 31P NMR spectrum responded very rapidly to the onset of ischemia, [Na+]i measured by 23Na NMR increased gradually but steadily at about 1.0 mM/min during early (up to 15 minutes) ischemia. These observations demonstrate that a rise in intracellular sodium does occur during early ischemia, that TmDOTP5- can be applied in vivo for analysis of intracellular sodium in the ischemic liver, and that 31P NMR spectroscopy is very sensitive to early ischemic injury.

Received 9 June 1995; accepted in final form 24 April 1996.
APS Manuscript Number A614-5.
Article publication pending Journal of Applied Physiology.
ISSN 1080-4757 Copyright 1996 The American Physiological Society.
Published in APStracts on 28 May 96